Combustion Synthesis of Nano CeO2 and its Application as a Catalytic Agent in Peptidomimetics
Authors
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Department of Chemistry, Siddaganga Institute of Technology, B.H. Road, Tumakuru-572 103, Karnataka ,IN
H.S. Lalithamba
DOI:
https://doi.org/10.18311/jmmf/2023/43182Keywords:
Amino Acyl Chlorides, Combustion Method, Fmoc/Cbz-Protected Amino Acids, Sodium Azide, Triazole.Abstract
An eco-friendly cerium oxide nanoparticle was prepared through a solution combustion system with a novel fuel plant seed source Albizzia richardiana. The synthetic technique involves the Albizzia richardiana plant seeds as a fuel and cerium nitrate as an oxidizer (basis of cerium) was added in stoichiometric quantity in a well washed silica crucible and stirred for several minutes until persistent uniform solution was made. Then the mixture was kept in a heat up heating chamber at 500 °C. After dehydration and decomposition of homogeneous solution, the obtained CeO2 nanoparticles were thoroughly characterized using FT-IR, XRD and SEM morphological analysis. The synthesized nano CeO2 was a better catalytic agent for the production of Nα-Fmoc/Cbz-keto-1,2,3-triazole equivalents through the three-constituent reaction between amino acyl chloride equivalents of Fmoc/Cbz-protected amino acids, phenyl acetylene and sodium azide. Keto-1,2,3-triazoles were set upon by refluxing amino acyl chlorides with NaN3 and phenyl acetylene in presence of CeO2 nano particles in methanol. After a simple workup, the desired products obtained were fully categorized by FTIR, HRMS, proton and 13C NMR techniques.
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