Application of Metal Oxide in Litho-Vanadium Glasses Containing Non-Magnetic Metal Ions: Physical and Optical Properties Analysis

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Authors

  • Basappa .
     Department of Physics, Maharani Cluster University, Bangalore - 560001, Karnataka ,IN
  • Karanam Madhavi
     Department of Physics, Maharani Cluster University, Bangalore - 560001, Karnataka ,IN
  • V. C. Veeranna Gowda
     Department of Physics, Maharani Cluster University, Bangalore - 560001, Karnataka ,IN
  • N. Hanumantharaju
     Department of Physics, Maharani Cluster University, Bangalore - 560001, Karnataka ,IN

DOI:

https://doi.org/10.18311/jmmf/2023/35750

Keywords:

Basicity, Lithium, Metal Oxide, Refractive Index

Abstract

Sodium-modified litho-vanadium glasses containing non-magnetic Aluminium ions of composition 50Li2CO3 - (30-X) Na2 CO3- 20V2O5 -xAl2O3 (30 ≤ x ≥ 5) (LNVA) glasses were prepared by melt quenching technique. The density of the glass samples was measured and found to increase with the Aluminium content of the glass matrix. The measured values of refractive index and polaron radius of the glass network show opposite behaviour with an increase of Aluminium content. Through band gap energy and refractive index, Oxide ion polarizability and electronic polarizability were determined by using the Lorentz-Lorenz equation. The value of Oxide ion polarizability and electronic polarizability is found to be decreased with decreasing band gap energy and increasing refractive index. The value of optical basicity was measured using electronic polarizability and is found to be decreased with decreasing inter-nuclear distance. The band gap energy values of the glass network were found to decrease from 3.241 to 2.134 eV. The metallisation criterion of the glass material was calculated and found to decrease with Aluminium content.

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Published

2024-01-12

How to Cite

., B., Madhavi, K., Gowda, V. C. V., & Hanumantharaju, N. (2024). Application of Metal Oxide in Litho-Vanadium Glasses Containing Non-Magnetic Metal Ions: Physical and Optical Properties Analysis. Journal of Mines, Metals and Fuels, 71(11), 1919–1924. https://doi.org/10.18311/jmmf/2023/35750

Issue

Volume 71, Issue 11, November 2023

Section

Articles

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Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

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Received 2023-11-30
Accepted 2023-12-22
Published 2024-01-12

 

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