Boronic Acid Functionalized Zirconium based MOF for the Complete Adsorptive Removal of Alizarin Dye

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Authors

  • S. G. Prasannakumar
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru-560054, Karnataka ,IN
  • K. S. Asha
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru - 560054, Karnataka ,IN
  • S. P. Smrithi
     Department of Chemistry, M.S. Ramaiah College of Arts, Science and Commerce, MSRIT Post, MSR Nagar, Bengaluru - 560054, Karnataka ,IN

DOI:

https://doi.org/10.18311/jmmf/2023/43601

Keywords:

11B NMR, Metal-Organic Framework, Mixed-Ligand, Organic Pollutants, Solvothermal

Abstract

Nowadays, one of the severe problems that threaten the survival of human beings is water pollution. Water pollution caused by diverse poisonous compounds, specifically hydroxyl aromatic compounds and their derivatives have been evident and prominent environmental issue. In this work, an adsorptive method to remove the hydroxyl aromatic compounds particularly catechol based Alizarin red S dye by the activated metal organic framework have been attempted. The nano scale Zr-UiO-66 was synthesized using terephthalic acid as ligand, 4-carboxy phenyl boronic acid as coordination modulator and the morphology of the nano crystals was octahedral. The as-synthesized new metal organic framework Zr-UIO-66 after adsorption confirms the existence of boronic acid and structural stability after the incorporation of the boronic acid group using adsorption studies such as 11B NMR, PXRD, UV, IR and TGA. The zirconium based MOFs are very important in terms of their stability in water. These MOFs are largely used for gas separation, storage, sensing and degradation of chemical warfare agents, etc. The control of size of these MOFs to nano regime can be achieved using the monocarboxylic acids like acetic acid, benzoic acid. A mixed-ligand approach was implemented in this work.

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Published

2024-05-24

How to Cite

S. G. Prasannakumar, Asha, K. S., & Smrithi, S. P. (2024). Boronic Acid Functionalized Zirconium based MOF for the Complete Adsorptive Removal of Alizarin Dye. Journal of Mines, Metals and Fuels, 71(12A), 404–409. https://doi.org/10.18311/jmmf/2023/43601

Issue

Volume 71, Issue 12A , 2023

Section

Articles

License

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

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