Interaction of a Cationic Surfactant with an Oppositely Charged Polymer

Authors

  • Soumen Ghosh Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal
  • Arpan Mal Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal
  • Tanushree Chakraborty Centre for Surface Science, Department of Chemistry, Jadavpur University, Kolkata – 700032, West Bengal
  • Gobinda Chandra De
  • Daniel Gerrard Marangoni Department of Chemistry, St. Francis Xavier University, Antigonish, Nova Scotia, B2G 2W5

DOI:

https://doi.org/10.18311/jsst/2016/14746

Keywords:

Anionic Polymer, Cationic Surfactant, Electrostatic Interaction, Hydrophobic Interaction, Micellization

Abstract

The interactions between the cationic surfactant Dodecyltrimethylammonium Bromide (DTAB) and anionic polymer sodium carboxymethyl cellulose (Na-CMC) in aqueous medium were studied at 300K over different concentrations of Na-CMC by tensiometry, conductometry, viscometry, turbidimetry and fluorimetry. Aggregation of surfactant was attained in two steps, the first being the monomeric adsorption of surfactants on anionic sites of the polymer saturating at lower concentrations of surfactant and the second one being the formation of micelles by surfactants at higher concentrations. Mainly, two types of interactions prevailed throughout namely, electrostatic and hydrophobic interactions. Due to the variation of the interactions depending on the concentrations of polymer, there has been considerable differences in the behavioural pattern of the profiles for the lower concentrations of polymer compared to that of the upper ones.

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Published

2017-04-05

How to Cite

Ghosh, S., Mal, A., Chakraborty, T., De, G. C., & Marangoni, D. G. (2017). Interaction of a Cationic Surfactant with an Oppositely Charged Polymer. Journal of Surface Science and Technology, 32(3-4), 107–114. https://doi.org/10.18311/jsst/2016/14746