Ecofriendly Synthesis and Characterization of Magnesium based Metal - Organic Frame Work

Jump To References Section

Authors

  • O. Lekshmy
     Post Graduate and Research Centre, Mahatma Gandhi College, Thiruvananthapuram – 695004, Kerala ,IN
  • K. S. Beena Kumari
     Department of Chemistry, All Saints’ College, University of Kerala, Thiruvananthapuram – 695007, Kerala ,IN
  • R. Sudha Devi
     Post Graduate and Research Centre, Mahatma Gandhi College, Thiruvananthapuram – 695004, Kerala ,IN

DOI:

https://doi.org/10.18311/jsst/2021/28590

Keywords:

Benzenedicarboxylic Acid, Clitoria ternatea, Microwave, FT-IR, SEM

Abstract

Magnesium based metal - organic Framework (MOF) was synthesized by using Benzene Di-Carboxylic acid (BDC), MgSO4.7H2O and a flower extract of Clitoria ternatea. The prepared MOF was characterized by FTIR spectrum, SEM-EDS, XRD, DLS and PL Spectrum. The crystalline nature of the synthesized MOF was revealed in XRD patterns. The nano particle nature of the MOF was confirmed from the SEM pictures. FT-IR spectra showed a peak at 520cm-1 designated characteristic absorption bands of synthesized Mg-MOF nano particles. The zeta potential value showed that the surface charge of the synthesized MOF is neutral and hence disperse in solution without having any tendency for agglomeration and coagulation on standing. The photoluminescence spectra indicated luminescent nature and hence this nano crystalline MOF finds very good application as luminescent material and as sensing material.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Downloads

Published

2023-02-15

How to Cite

Lekshmy, O., Beena Kumari, K. S., & Sudha Devi, R. (2023). Ecofriendly Synthesis and Characterization of Magnesium based Metal - Organic Frame Work. Journal of Surface Science and Technology, 37(3-4), 203–209. https://doi.org/10.18311/jsst/2021/28590

Issue

Volume 37, Issue 3-4, December 2021

Section

Articles
Crossref
Scopus
Google Scholar
Europe PMC
Received 2021-09-07
Accepted 2022-09-06
Published 2023-02-15

 

References

O. Shekhah, J. Liu, R. A. Fischer, C. Woll. Chem. Soc. Rev., 40, 1081 (2011). https://doi.org/10.1039/c0cs00147c. PMid:21225034. DOI: https://doi.org/10.1039/c0cs00147c

T. Ghanbari, F. Abnisa, W. Daud, D.W.M.A. Wan. Sci. Tot. Environ., 707, 10, 13500 (2019). https://doi.org/10.1016/j.scitotenv.2019.135090. PMid:31863992. DOI: https://doi.org/10.1016/j.scitotenv.2019.135090

F. Al-Rowili, A. Jamal, M. S. Ba-Shamakh, A. Rana. ACS Sustain. Chem. Eng., 6, 15895 (2018). https://doi.org/10.1021/acssuschemeng.8b03843. DOI: https://doi.org/10.1021/acssuschemeng.8b03843

Q. Wang, D. Astruc. Chem. Rev., 120, 1438 (2019). https:// doi.org/10.1021/acs.chemrev.9b00223. PMid:31246430. DOI: https://doi.org/10.1021/acs.chemrev.9b00223

J. Ren, H.W. Langmi, B.C. North, M. Mathe. Int. J. Energy Res., 39, 607 (2014). https://doi.org/10.1002/er.3255. DOI: https://doi.org/10.1002/er.3255

J.R. Li, R.J. Kuppler, H.C. Zhou. Chem. Soc. Rev., 38, 1477 (2009). https://doi.org/10.1039/b816681c, https://doi. org/10.1039/ b802426j. PMid:19384449. DOI: https://doi.org/10.1039/b802426j

S. Yang, V.V. Karve, A. Justin, I. Kochetygov, J. Espín, M. Asgari, W. L. Queen et al. Coord. Chem. Rev., 427, 213525 (2021). https://doi.org/10.1016/j.ccr.2020.213525, https://doi.org/10.1016/j.ccr.2020.213551. DOI: https://doi.org/10.1016/j.ccr.2020.213525

Y.Y. Tong, Y.F Li, L. Sun, R. Yang, S. Zhang, Y. Fu, R. Chen. Sep. Purif. Technol., 250, 117142 (2020). https://doi. org/10.1016/j.seppur.2020.117142. DOI: https://doi.org/10.1016/j.seppur.2020.117142

V.J. Pastore, T.R. Cook, J. Rzayev. Chem Mater., 30, 8639 (2018). https://doi.org/10.1021/acs.chemmater.8b03881. DOI: https://doi.org/10.1021/acs.chemmater.8b03881

M.K. Buschbaum, F. Beuerle, C. Feldmann. Microporous Mesoporous Mater., 216, 171 (2015). https://doi.org/10.1016/j.micromeso.2015.03.036. DOI: https://doi.org/10.1016/j.micromeso.2015.03.036

C. Qing, Y. Yiting, W. Liju, G. Zhiqi, Z. Yunchun, W. Dongmei, L.A. Chunxia. Int. J. Inorg. Chem., 646, 437 (2020).

P.A. Ochoa, G. Givaja, P.J.S. Miguel, O. Castillo, F. Zamora. Inorg. Chem. Commun., 10, 921 (2007). https://doi.org/10.1016/j.inoche.2007.04.024. DOI: https://doi.org/10.1016/j.inoche.2007.04.024

D. Buso, K.M. Nairn, M. Gimona, A.J. Hill, P. Falcaro. Chem. Mater., 23, 929 (2011). https://doi.org/10.1021/cm101519s. DOI: https://doi.org/10.1021/cm101519s

X. Wu, Z. Bao, B. Yuan, J. Wang, Y. Sun, H. Luo, S. Deng. Microporous Mesoporous Mater., 180, 114 (2013). https://doi.org/10.1016/j.micromeso.2013.06.023. DOI: https://doi.org/10.1016/j.micromeso.2013.06.023

F. Asadi, H. Forootanfar, M. Ranjbar, A. Asadipour. Arab. J. Chem., 13, 7820 (2020). https://doi.org/10.1016/j.arabjc.2020.09.013. DOI: https://doi.org/10.1016/j.arabjc.2020.09.013

J.J. Richardson, K. Liang. Small, 14, 1702958 (2017). https:// doi.org/10.1002/smll.201702958. PMid:29168918. DOI: https://doi.org/10.1002/smll.201702958

G.K. Oguis, E.K. Gilding, M.A. Jackson, D. Caik. J Front. Plant Sci., 10, 645 (2019). https://doi.org/10.3389/fpls.2019.00645. PMid:31191573 PMCid:PMC6546959. DOI: https://doi.org/10.3389/fpls.2019.00645

S.S. Swain, K.K. Rout, P.K. Chand. Appl. Biochem. Biotechnol., 168, 487 (2012). https://doi.org/10.1007/s12010-012-9791-8. PMid:22843061. DOI: https://doi.org/10.1007/s12010-012-9791-8

S. Rasha Saad, X.T. Brian Sheng, A. Fadli et al. J. Plant Biol., 4, 1 (2015).

H.A. Salam, H.H. El- Maghrbi, F. Zahran, T. Zaki. Korean J Chem Eng., 37, 670 (2020). https://doi.org/10.1007/s11814- 020-0491-8.

N. John Sushma, D. Prathyusha, G. Swathi, T. Madhavi, B. Deva Prasad Raju, K. Mallikarjuna, Hak-Sung Kim. Appl. Nanosci., 6, 437 (2016). https://doi.org/10.1007/s13204- 015-0455-1. DOI: https://doi.org/10.1007/s13204-015-0455-1

J.Z. Chan, R. Rasit Ali, K. Shameli, M.S.N. Salleh, K.X Lee, E.D. Mohamed Isa. IOP Conf. Ser: Mater. Sci. Eng., 808, (2020). https://doi.org/10.1088/1757-899X/808/1/012036. DOI: https://doi.org/10.1088/1757-899X/808/1/012036

T. K.N. Tran, H.L. Ho, H.V. Nguyen, B.T. Tran, T.T. Nguyen, P.Q.T. Bui, L.G. Bach. Open Chem. J., 20, 52 (2021). https://doi.org/10.1515/chem-2021-0110. DOI: https://doi.org/10.1515/chem-2021-0110

K. Sreekanth Mahadeva, J. Fan, A. Biswas, K. S. Sreelatha, L. Belova, K.V. Rao. Nanomater., 3, 486 (2013). https://doi.org/10.3390/nano3030486. PMid:28348346 PMCid: PMC5304652. DOI: https://doi.org/10.3390/nano3030486