Micellar Effect on the Hydrolysis of Imines, Kinetics and Mechanism of Alkaline Hydrolysis of N-Salicylidene-2-Amino Thiazole and N-salicylidene-2-Aminopyridine in the Presence of Cetyl Trimethyl Ammonium Bromide

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Authors

  • Department of Chemistry, Utkal University, Bhubaneshwar-751 004 ,IN
  • Department of Chemistry, Utkal University, Bhubaneshwar-751 004 ,IN
  • Department of Chemistry, Utkal University, Bhubaneshwar-751 004 ,IN

DOI:

https://doi.org/10.18311/jsst/1985/2181

Abstract

The effect of cetyl trimethyl ammonium bromide on the kinetics of base hydrolysis of the title schiff bases was investigated in 5% v/v methanol-water medium at 35°C, 0.0002 ≤ (CTAB)T ≤ 0.02 mol dm-1, and 0.01 ≤ [OH]T ≤ 0.07 mol dm-3 (I=01 mol dm-3). The imine anions bound to the CTAB micelle are observed to undergo hydrolysis at rates much slower than in the aqueous pseudo phase. This indirectly supports our earlier conclusion that the hydrolysis of these anions involve participation of the intramolecular general base catalysis of the phenoxide group.

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Published

1985-01-01

How to Cite

Dash, A. C., Dash, B., & Panda, D. (1985). Micellar Effect on the Hydrolysis of Imines, Kinetics and Mechanism of Alkaline Hydrolysis of N-Salicylidene-2-Amino Thiazole and N-salicylidene-2-Aminopyridine in the Presence of Cetyl Trimethyl Ammonium Bromide. Journal of Surface Science and Technology, 1(1), 59–62. https://doi.org/10.18311/jsst/1985/2181

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